Advances in Carbohydrate Chemistry, 1 by Ward W Pigman; M L Wolfrom

By Ward W Pigman; M L Wolfrom

ADVANCES IN CARBOHYDRATE CHEMISTRY VOL 1.

content material: entrance conceal; Advances in Carbohydrate Chemistry, quantity 1; Copyright web page; members to quantity I; Editors' Preface; Contents; bankruptcy 1. The Fischer Cyanohydrin Synthesis and the Configurations of Higher-carbon Sugars and Alcohols; bankruptcy 2. The Altrose workforce of gear; bankruptcy three. Carbohydrate Orthoesters; bankruptcy four. Thio- and Seleno-Sugars; bankruptcy five. The Carbohydrate elements of the Cardiac Glycosides; bankruptcy 6. Metabolism of the Sugar Alcohols and Their Derivatives; bankruptcy 7. The Chemistry of the Nucleic Acids; bankruptcy eight. The Fractionation of Starch.
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54 1‘111. e Derivatives. . . . . . . . . . . . . 57 IX. The 6-Desoxyaltroses. . . . . . . . . . . . . . . . . . . . . . . . X. The Alluloses.. . . . . . . . . . . . . . . . . . . . . . . . . . . XI. Cakiiirn D-Ahonate from D-&d&LCtoFR Itnd from Pectin. . . . . . XII. Compounds Possibly Related to Altrow XIII. Table I. D- and L-Altrose and Derivatives. . . . . . . . . . . . . . . XIV. Table 11. NeOlartOw. Celtmbiose.

54 1‘111. e Derivatives. . . . . . . . . . . . . 57 IX. The 6-Desoxyaltroses. . . . . . . . . . . . . . . . . . . . . . . . X. The Alluloses.. . . . . . . . . . . . . . . . . . . . . . . . . . . XI. Cakiiirn D-Ahonate from D-&d&LCtoFR Itnd from Pectin. . . . . . XII. Compounds Possibly Related to Altrow XIII. Table I. D- and L-Altrose and Derivatives. . . . . . . . . . . . . .

Yoalc. Octitol is not meso 3 pts. 95% ale. Identical with 8 c3 *4 3 3 2 3 3 $ 36 C. S. HUDSON tion, recrystallization from 100 parts of 95% alcohol ; D-gluco-Didoheptitol heptabenzoate, m. p. 5) in chloroform, recrystallization from 125 parts of 95% alcohol. The melting point of the latter substance agrees with Philippe's valueM; the rotation is the first record. The heptabenzoate of the meso alcohol is a new substance. Pure allitol (meso configuration; m. p. 15S151") was described for the first time by Lespieau and Wiemann,"S who synthesized it by the hydroxylation of one of the stereoisomaric forms of divinylglycol.

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