Advanced Techniques in Art Conservation by Andrew J. Clark

By Andrew J. Clark

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Khanjian. H. Gas chromatographic determination of the fatty acid and glycerol content of lipids IV. Evaporation of fatty acids and the formation of ghost images by framed oil paintings. ; Brown, J. In Preprints of 12th Triennial Meeting of ICOM Committee for Conservation, James and James: London, 1999. LYON, pp 242-247. htm. Vol. 43, No. 6 June 2010 715-727 ACCOUNTS OF CHEMICAL RESEARCH 727 In Situ Noninvasive Study of Artworks: The MOLAB Multitechnique Approach COSTANZA MILIANI,*,† FRANCESCA ROSI,‡ BRUNETTO GIOVANNI BRUNETTI,†,‡ AND ANTONIO SGAMELLOTTI†,‡ † Istituto CNR di Scienze e Tecnologie Molecolari (CNR-ISTM), c/o Dipartimento di Chimica, Universita` degli Studi di Perugia, via Elce di Sotto 8, I-06123 Perugia, Italy, and ‡Dipartimento di Chimica, Universita` degli Studi di Perugia, via Elce di Sotto 8, I-06123 Perugia, Italy RECEIVED ON JANUARY 9, 2010 CON SPECTUS D riven by the need to study precious and irreplaceable artworks without compromising their integrity, researchers have undertaken numerous efforts to develop noninvasive analytical tools and methodologies that can provide a chemical description of cultural heritage materials without any contact with the object.

Lastly, dealing with proteins, lipids, and saccharides could involve a high level of environmental contamination. Blanks must thus be run frequently and the corresponding LOD (limit of detection) and LOQ (limit of quantitation) calculated, in order to avoid any misleading interpretation when the amount of analytes determined is not significant. 0. This profile is similar to that of egg, and in fact, when this sample is processed with the PCA method, it falls very close to the egg cluster. 30 µg; this indicated that the sample did not contain significant level of proteinaceous binder, and the amino acids detected were likely due to environmental contamination and not to the presence of egg.

43, No. 6 June 2010 715-727 ACCOUNTS OF CHEMICAL RESEARCH 723 Strategies for Characterizing Organic Paint Media Colombini et al. speed, and solubility of the metal carboxylates in the paint media and in the cleaning solvents could alter the amounts of acids that are recovered in the analysis. 19 As a result of all these factors, the widely used P/S parameter should be very carefully considered, and in our opinion, further research is needed to define the criteria for reliably identifying the botanical source of a drying oil in a paint sample.

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